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With the extensive construction of photovoltaic charging station infrastructure, not only provided convenience for the electric vehicles users, but also brought great challenges for its management. In order to achieve more effective management of photovoltaic charging stations, based on the analysis of the data communication scheme of distributed photovoltaic charging station, this paper designs a kind of Web real-time monitoring platform. Based on ZigBee technology, GPRS-DTU technology and HTTP protocol in this platform, we designed DC charging pile wireless sensor data acquisition scheme, while deployed the database server and the Web server in order to overcome the problem of charging pile unattended, to achieve centralized control of distributed systems, and we designed Android APP for charging reservation users to monitoring, alerts and other functions to improve user experience. And the experimental verification of the system is carried out. After verification, the design scheme can realize the real-time data acquisition and Web centralized control of distributed PV charging station. Provides an effective technical solution for the unattended and remote monitoring of the charging stations.